Quantum theory evolved as a new branch of theoretical
physics during the first few decades of the 20th century in an endeavour to
understand the fundamental properties of matter. It began with the study of the
interactions of matter and radiation. Certain radiation effects could neither
be explained by classical mechanics, nor by the theory of electromagnetism. In
particular, physicists were puzzled by the nature of light. Peculiar lines in
the spectrum of sunlight had been discovered earlier by Joseph von Fraunhofer
(1787-1826). These spectral lines were then systematically catalogued for
various substances, yet nobody could explain why the spectral lines are there
and why they would differ for each substance. It took about one hundred years,
until a plausible explanation was supplied by quantum theory.
Quantum theory is
about the nature of matter.
Quantum mechanics (QM – also known as quantum physics, or
quantum theory) is a branch of physics dealing with physical phenomena at
microscopic scales, where the action is on the order of the Planck constant.
Quantum mechanics departs from classical mechanics primarily at the quantum
realm of atomic and subatomic length scales. Quantum mechanics provides a
mathematical description of much of the dual particle-like and wave-like behavior
and interactions of energy and matter.
In advanced topics of quantum mechanics, some of these
behaviors are macroscopic and only emerge at extreme (i.e., very low or very
high) energies or temperatures. The name quantum mechanics derives from the
observation that some physical quantities can change only in discrete amounts
(Latin quanta), and not in a continuous (cf. analog) way. For example, the
angular momentum of an electron bound to an atom or molecule is quantized. In
the context of quantum mechanics, the wave–particle duality of energy and
matter and the uncertainty principle provide a unified view of the behavior of
photons, electrons, and other atomic-scale objects.
Applications
Quantum mechanics had enormous success in explaining many of
the features of our world. The individual behaviors of the subatomic particles
that make up all forms of matter (electrons, protons, neutrons, photons, and
others) can often only be satisfactorily described using quantum mechanics.
Quantum mechanics has strongly influenced string theories, candidates for a
Theory of Everything and the multiverse hypotheses.
Quantum mechanics is also critically important for
understanding how individual atoms combine covalently to form molecules. The
application of quantum mechanics to chemistry is known as quantum chemistry.
Relativistic quantum mechanics can, in principle, mathematically describe most
of chemistry. Quantum mechanics can also provide quantitative insight into
ionic and covalent bonding processes by explicitly showing which molecules are
energetically favorable to which others, and the magnitudes of the energies
involved. Furthermore, most of the calculations performed in modern
computational chemistry rely on quantum mechanics.
A working mechanism of a resonant tunneling diode device,
based on the phenomenon of quantum tunneling through potential barriers
A great deal of modern technological inventions operates at
a scale where quantum effects are significant. Examples include the laser, the
transistor (and thus the microchip), the electron microscope, and magnetic
resonance imaging (MRI). The study of semiconductors led to the invention of
the diode and the transistor, which are indispensable parts of modern
electronics systems and devices.
Researchers are currently seeking robust methods of directly
manipulating quantum states. Efforts are being made to more fully develop
quantum cryptography, which will theoretically allow guaranteed secure
transmission of information. A more distant goal is the development of quantum
computers, which are expected to perform certain computational tasks
exponentially faster than classical computers. Another active research topic is
quantum teleportation, which deals with techniques to transmit quantum information
over arbitrary distances.
Quantum tunneling is vital to the operation of many devices
- even in the simple light switch, as otherwise the electrons in the electric
current could not penetrate the potential barrier made up of a layer of oxide.
Flash memory chips found in USB drives use quantum tunneling to erase their
memory cells.
While quantum mechanics primarily applies to the atomic
regimes of matter and energy, some systems exhibit quantum mechanical effects
on a large scale - super fluidity, the frictionless flow of a liquid at
temperatures near absolute zero, is one well-known example. Quantum theory also
provides accurate descriptions for many previously unexplained phenomena, such
as black body radiation and the stability of the orbitals of electrons in
atoms. It has also given insight into the workings of many different biological
systems, including smell receptors and protein structures. Recent work on
photosynthesis has provided evidence that quantum correlations play an
essential role in this basic fundamental process of the plant kingdom. Even so,
classical physics can often provide good approximations to results otherwise
obtained by quantum physics, typically in circumstances with large numbers of
particles or large quantum numbers.
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